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Unfortuitously, the part and distribution advancement of C-dopant remains not fully recognized, especially in practical manufacturing products. In this report, because of the help of advanced spherical aberration corrected transmission electron microscopy, the process of microstructure advancement manipulated by C-dopant is clearly defined. The grain-inner C atoms distinctly boost cationic migration energy barriers, that is might basis for marketing the thermal stability of metastable face-c