https://www.selleckchem.com/products/c75.html
Asymmetric Pd-catalyzed Tsuji-Trost-type allylation is an important catalytic reaction toward chiral natural and unnatural product syntheses. We successfully modified a desalt-type reaction using allyl ester or halide to a dehydrative one using allylic alcohol via the establishment of two redox-mediated donor acceptor bifunctional catalyst systems. These systems were cationic CpRu-Cl-Napy-PyCOOH and cationic CpRu-Naph-diPIM-dioxo-iPr/p-TsOH and were designed on the basis of the soft ruthenium and hard Brønsted acid combined catalyst concept
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