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Operando/in situ spectroscopy and STEM imaging reveals that the strongly improved activity, by elements of 5 and 14 for CO and CO2 methanation, is accompanied by a flattening associated with Ru nanoparticles while the development of very fundamental hydroxylated alumina websites. We suggest an adjustment regarding the metal-support interactions (MSIs) whilst the beginning associated with the increased activity, brought on by adjustment of this Al