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Overall, pain was moderately high (mean pain intensity in past week=5.2 (Standard Deviation (SD)=1.6) and mean pain interference=5.5 (SD=2.2)). Pain-related anxiety was high (mean=47.0 (SD=22.2)) and self-efficacy was low (mean=3.8 (SD=1.6)). PASS utilizes an innovative smoking and pain intervention to promote smoking cessation among Veterans with chronic pain. Baseline characteristics reflect a socioeconomically vulnerable population with a high burden of mental health comorbidities. PASS utilizes an innovative smoking and pain interventio