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Using this background at heart, a brand new photosensitizer [Ru(S-Sbpy)(bpy)2]2+ (12+) designed with a disulfide functionalized bpy ligand (S-Sbpy, bpy = 2,2'-bipyridine) ended up being synthesized and it has already been comprehensively studied, including structural characterization by X-ray diffraction. In-depth electrochemical research has revealed that the S-Sbpy ligand in 12+ can be paid off twice at moderate potentials (around -1.1 V vs Fc+/