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The introduction of photothermal effect activated by infrared light provides general and robust strategy to promote the PEC performance of photoanodes.The charge separation and transfer are the major issues dominating the under-laying energy conversion mechanism for photocatalytic system. Construction of semiconductor-based heterojunction system considered to be viable option for boosting the spatial charge separation and transfer in the photocatalytic water splitting system. Here, we design a ternary heterojunction of Ti3C2/N, S-TiO2