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The 3D spatial structure of dewatered sludge cakes analyzed by computed tomography technology showed that the number of pores of the dewatered sludge cake treated by HACPAM 3 was smaller than that of the cake treated by CPAM, with a reduction in the porosity of 68.8%, resulting in a better hydrophobic effect. In addition, the mechanism of HACPAM improving the dewatering performance is discussed.Flax straw biochar (FSBC)-supported nanoscale zero-valent iron (nZVI) composite (nZVI-FSBC) combining the advantages of nZVI and biochar was syn