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ix Arrow, male sex, and longer follow-up duration.Solvent-corrected reduced isotropic spectra of carbonate and bicarbonate in light and heavy water have been measured from 150 to 325 °C at 21 MPa using a confocal Raman microscope and a custom-built titanium flow cell with sapphire windows. The positions of the symmetric vibrational modes of CO32- and HCO3-/DCO3- were compared to density functional theory (DFT) calculations with a polarizable continuum model in light and heavy water. The experimental Raman peak positions shifted linearly
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