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Expectedly, the interaction involving the different PL centers hinges on the shared arrangement therefore the type of connecting. To get insights into such a communication, time-dependent thickness functional principle (TD-DFT) calculations were performed for all (N-doped/O-functionalized) polyaromatic hydrocarbons (PAHs) as representative models for the core/surfaces PL says while the prototypical molecular fluorophore (MF) 5-oxo-1,2,3,5-tetrahydroimidazo-[1,2-α]-p