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niversal nonselective pTX-pulses were successfully computed using GRAPE. Performance gains as compared to k T -points were validated numerically and experimentally for three imaging protocols. In its current implementation, the computational burden of GRAPE limits its use to applications where pulse computations are not subject to time constraints.Single atoms have been widely applied as efficient catalysts in various catalytic systems due to its high selectivity for certain products, which is induced by a uniform coordinate environment o