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ng-term carbon sequestration.Heterogeneous electron-Fenton processes have been regarded as promising, environmentally friendly techniques for the removal of refractory organics. A new strategy has been brought forward for an electron-Fenton-like process with in situ H2O2 production, but regarding the catalysts, their geometric stability, H2O2 selectivity, and applicability under high pH values still need to be improved. Herein, bifunctional catalysts were proposed for a heterogeneous Fenton-like reaction by introducing Fe atoms into defe