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Results showed that the proposed treatment could be an alternative for arsenic and selenium removal (70 μg/L and 0.5 μg/L permeate concentrations, respectively) to achieve mining discharge limits according to regulations.Controlling the particle size and aggregation of nanosheet layers in layered double hydroxides (LDHs) is critical for their application. Herein, we report the preparation of Mg-Fe LDH through a co-precipitation method. The LDH was embedded using polyacrylamide (PAM) and polyvinyl alcohol (PVA; the LDH was designated as