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The results are compared to well-known classification techniques, which shows that the proposed technique outperforms the others in terms of the G-mean having the value of 78% compared to 75% for KNN and less than 50% for the other techniques.Glycero- and sphingo-lipids are important in plasma membrane structure, caloric storage and signaling. An un-targeted lipidomics approach for a cohort of critically ill pediatric intensive care unit (PICU) patients undergoing multi-organ dysfunction syndrome (MODS) was compared to sedation controls.