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Finally, more negative of the onset potential, the electrode attracts additional reactants, displacing the stationary products and enabling steady state current. This work shows that the integration of a vibrational Stark-shift probe with a proton donor provides critical insight into the interplay between interfacial electrostatics and heterogeneous chemical reactions. Such insights cannot be obtained from electrochemical measurements alone.The heterogeneous Fenton process has been widely applied though some aspects of this process are
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