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Construction of Z-scheme heterojunction photocatalyst for CO2 photoreduction shows great significance as it holds strong redox ability and high charge separation efficiency. In this work, we developed a Z-scheme heterojunction photocatalyst graphitic carbon nitride (g-C3N4)/basic bismuth borate (Bi2O2[BO2(OH)]) by a simple high-energy ball milling method. The structure, surface element distribution and morphology of the composite samples were systematically analyzed. The photocatalytic performance of the samples was surveyed by CO2 redu