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This work offers a novel strategy towards wastewater decontamination applications and further understanding the relationship between piezocatalysis, morphology, and piezocatalytic mechanism in piezoelectric materials.Self-powered ultraviolet (UV) photodetectors (PDs) based on ZnO heterojunctions have attracted more attention due to the simple preparation and excellent photoresponse performance without any power supply. The self-powered UV PDs based on NiO nanoflakes/ZnO nanorod arrays (NRs) heterojunctions were fabricated by a low-cost, si