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Alumina-supported Fe-Mn oxide catalysts were synthesized by the incipient wetness impregnation method. The catalysts were characterized using various characterization techniques such as surface area, XRD, H2-TPR, and Raman spectral analysis. The adsorption (Cy-H, CO2) and oxidation of cyclohexane (Cy-H) were conducted by considering the in situ DRIFTS studies. The iron-impregnated catalyst possessed a higher surface area than the manganese-impregnated catalyst. The manganese-oxides remained dispersed in the support an