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CO2 hydrogenation for syngas can alleviate the pressure of un-controlled emissions of CO2 and bring enormous economic benefits. Advantageous Ni-catalysts have good CO2 hydrogenation activity and high CO selectivity merely over 700 °C. Herein, we introduced Cu into Ni catalysts, which were evaluated by H2 -TPR, XRD, BET, in-situ XPS and CO2 -TPD, and their CO2 hydrogenation activity and CO selectivity were significantly affected by the Ni/Cu ratios, which was rationalized by the synergistic effect of bimetallic catalysts. In addition, th