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The kinetics of oxidative cracking of n-hexane to light olefins using the lattice oxygen of VOx /SrO-γAl2 O3 catalysts has been investigated. Kinetic experiments were conducted in a CREC Riser Simulator (CERC Chemical Reactor Engineering Center), which mimics fluidized bed reactors. The catalyst's performance is partly attributed to the moderate interaction between active VOx species and the SrO-γAl2 O3 support. This moderate interaction serves to control the release of lattice oxygen to curtail deep oxidation. The incorporation of basic