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We believe that this is an interesting step toward patterning LHP nanocrystals at the nanoscale for device fabrication.A series of heteroleptic Cu(I) diimine complexes with different ancillary ligands and 6,6'-dimethyl-2,2'-bipyridine-4,4'-dibenzoic acid (dbda) as the anchoring ligand were self-assembled on TiO2 surfaces and used as dyes for dye-sensitized solar cells (DSSCs). The binding to the TiO2 surface was studied by hard X-ray photoelectron spectroscopy for a bromine-containing complex, confirming the complex formation. The perfo