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Based on the catalytic rate constant evaluation, the catalytic reduction efficiency for 4-NP is found to be superior for 2% weight Al2O3@Ag NF (92.9 × 10-3 s-1) as compared to the SiO2@Ag NF (29.3 × 10-3 s-1). Importantly, the enhanced catalytic efficiency of 2% weight Al2O3@Ag NF for 4-NP removal is much higher than other metal NPs based catalysts reported in the literature, signifying the importance of NF formulation-based catalysis.Invasive urothelial carcinomas of the bladder (UC characteristically show a loss of differentiation m