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The size, shape and structure of iron particles in iron electrode influence the electrochemical properties of Fe/air cells. In order to improve the electrochemical performance of Fe/air cells, an attempt has been made successfully to synthesize iron oxide particles with different surface morphologies and have been used as negative electrodes. Fe₂O₃ nanoparticles were synthesized by hydrothermal method, in which their different morphologies viz., hollow spheres, tubes and plates have been controlled by the concentration of precursors. A