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This work serves to present both the outstanding level of control in the precise synthesis and high potential for nanocomposite thin films in photo-electrocatalytic application.Functional hybrids comprising metallic nanostructures connected and protected by nonmetallic 2D materials are envisioned as miniaturized components for applications in optics, electronics, and magnetics. A promising strategy to build such elements is the direct writing of metallic nanostructures by focused electron beam induced processing (FEBIP) onto insulating