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Graphitic carbon nitride (g-C3N4) is a promising photocatalyst for water hydrogen evolution. Nonetheless, fast recombination of photogenerated electron-hole pairs and the slow kinetics of hydrogen production result in the unsatisfactory efficiency of solar hydrogen production. we address this issue by anchoring the cobalt phosphide (CoP) cocatalyst onto the one-dimensional boron doped g-C3N4 nanotube (B-CNNT) to construct B-N-Co surface bonding states in the B-CNNT/CoP photocatalyst. Spectroscopic measurement and density functional theo