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This study provided a new strategy for the toughening of geopolymer composites, which can promote the low-cost and efficient application of geopolymer composites in the field of building materials.Finding a non-destructive characterization method for cellular ceramics' compressive strength and fracture behavior has been a challenge for material scientists for years. However, for transparent materials, internal stresses can be determined by the non-destructive photoelastic measurements. We propose a novel approach to correlate the photo