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Concerning La2Mo2O9, there is no effect following the insertion of Bi, implying that the role of Bi is insignificant.Abundant pyridinic nitrogen in the triazine units of covalent triazine frameworks (CTFs) is very useful in various heterogeneous catalysis reactions. Herein, a tunable CTF platform with the same porous structure was designed and synthesized to study the interaction between palladium/platinum (Pd/Pt) and pyridinic nitrogen of CTFs. The smaller Pd nanoparticles were formed because of the stronger interaction between Pd and