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Among various charge-carrier ions for aqueous batteries, non-metal hydronium (H3 O+ ) with small ionic size and fast diffusion kinetics empowers H3 O+ -intercalation electrodes with high rate performance and fast-charging capability. However, pure H3 O+ charge carriers for inorganic electrode materials have only been observed in corrosive acidic electrolytes, rather than in mild neutral electrolytes. Herein, we report how selective H3 O+ intercalation in a neutral ZnCl2 electrolyte can be achieved for water-proton co-intercalated α-MoO3