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The relaxation properties are controlled by the polarization of the ferroelectric layer, and this polarization is used to control the amount by which the conductance levels increase during PPF operation and to enhance LTP characteristics. This study provides an important step toward the development of photonic synapses with tunable synaptic functions. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.High energy density is the major demand for next-generation rechargeable batteries, while the intrinsic low alkali metal adsorption of t