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With a NiFe layered-double-hydroxide electrocatalyst, ZABs on the basis of the asymmetric cathode deliver a little charge/discharge current space (0.81 V at 5.0 mA cm-2 ), a top power thickness, and a reliable cyclability (over 2000 cycles). This 3D reactive program strategy provides a feasible means for enhancing the air cathode kinetics and additional enlightens electrode styles for power devices involving multiphase electrochemical reactions. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.