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Combined with frontier electron density, the degradation pathway was deduced as follows destruction of azo bond, substitution of •OH, dehydrogenation and oxidation, opening-ring and mineralization. In EIEL-PEF, the concentration of oxalic acid and oxamic acid reached the maximum value 9.2 and 1.5 mg L-1 at 60 and 90 min, respectively. The photolysis of N-intermediates produced NH4+-N was released in more proportion than NO3--N and oxamic acid-N. The study indicated that PEF system has the potential to remove organic pollutants in aquatic
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