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The results from all four techniques were combined to understand changes in DOM chemical formulae. It was concluded that nitrogen-containing aromatic compounds and alkylbenzenes were oxidized by permanganate to form nitrogen-containing aliphatic compounds and benzoic acid-containing compounds. This work highlights how multiple ionization techniques coupled with UHR-MS can enable a more detailed characterization of DOM.Catalytic precipitation and subsequent electrochemical oxidation or reduction of a redox-active precipitate has been widel