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8 mg g-1 (107.5 mg g-1 NiHCF@3DC-2) and good cyclic regenerative performance. Moreover, the Na+ ions storage mechanism and the interfacial synergy of the NiHCF@3DC-2 were also explored by structure and electrochemistry analyses during the CDI process. Our work provides a promising redox-active intercalation electrode material to highly efficient hybrid capacitive deionization for brine.Stimuli-responsive nanoparticles (NPs), so-called "smart" NPs, possess great potentials in drug delivery. Presently, the intelligence of smart NPs is mainl