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In summary, these outcomes show that materials exhibit not just an even more stable structure but also better electrochemical performance after modification.Metallo-supramolecular polymer (MSP)-based electrochromic devices (ECDs) have drawn much interest due to their variable colors and attractive electrochromic (EC) properties. Nevertheless, fabrication of voltage-tunable multicolor ECDs utilizing solitary MSP is however hard to understand. We expected alternative introduction of two various red