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Diamond-structured colloidal photonic crystals are much sought-after for their applications in visible light management because of their ability to support a complete photonic band gap (PBG). However, their realization via self-assembly pathways is a long-standing challenge. This challenge is rooted in three fundamental problems the design of building blocks that assemble into diamond-like structures, the sensitivity of the PBG to stacking faults, and ensuring that the PBG opens at an experimentally attainable refractive index. Here we