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The synthesis and luminescence properties of a series of mono- and diaminocorannulenes are described herein. Their synthesis from halocorannulenes is straightforward. Evaluation of their luminescence leads to three surprising discoveries. First, a wide range of mono- and diaminocorannulenes are far more fluorescent in solution than corannulene itself, and 4a-j and 5a-e are also fluorescent in the solid state. Second, we have identified a diaminocorannulene possessing what we now regard as "typical" green-yellow fluorescence in solution