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OH was dominant radical, and contributed to nearly 86% of the overall ATZ removal. A total of five intermediate products of ATZ were identified, and ATZ degradation was achieved via de-alkylation and hydroxylation processes. An enhanced reaction mechanism for ATZ degradation by B-nZVI/FeS2/H2O2 process was proposed, and B-nZVI/FeS2/H2O2 process exhibited an excellect catalytic performance within four successive runs.Cystic echinococcosis (CE), which is caused by Echinococcus granulosus, is a worldwide helminthozoonosis that is highly endemic in the Tibet Au