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Besides, the surface characteristics of AC and Fe/AC before and after PS oxidation were evaluated by XPS and SEM. A quenching test used MeOH as an inhibitor and EPR spectra of free radicals were conducted to develop the proposed reaction mechanisms for PFOA oxidation. The sources of microplastics and other anthropogenic particles in freshwater are not well understood. The Greater Toronto Area, Canada's most populous urban area, offers a great study area for understanding the sources and pathways for microplastics to ent