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Besides, a phenomenon of oxygen launch and subsequent area lattice densification is seen, that is accountable for the big permanent capacity reduction during the initial cycle. Also, the air release is successfully suppressed by Fe replacement as a result of the formation of a unique Fe-(O-O) species, which successfully stabilizes the reversibility for the O2-/O2 n- redox at high running voltage. Our findings provide a new knowledge of the chemical development in layered transition metal