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The simulated pump-probe spectra provide support for current interpretations of two-photon photoemission experiments in closely related acene crystals such as tetracene and pentacene.Here, we report a de novo synthetic method toward β-2,6-dideoxypyranoglycosides. The key occasion may be the ruthenium-catalyzed regioselective olefin migration of dihydropyran allylic acetals to homoallylic acetals. In combination with various other metal-catalyzed reactions, this brand new protocol generated
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