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The rational design of multi-shelled hollow structured electrode materials is of great importance and has met with fundamental challenges in recent years. Herein, we demonstrate a combination approach of self-templating and sacrificial templating method for synthesizing double-shelled hollow nanoflower-structured V6O11@Ni(OH)2/NiOOH. Firstly, highly uniform vanadium-glycerate (VG) solid nanospheres are controllably synthesized and employed as the template, then Ni(OH)2/NiOOH nanosheets grow vertically on it, following with VG solid nano