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For all presented compounds, crystal structures are discussed in-depth. Furthermore, properties of 1, 3, and those of the three 1D coordination polymers, 2 Ag , 2 Cu , and 4, were investigated by UV-vis-NIR spectroscopy, cyclic voltammetry, and variable-temperature magnetic susceptibility, and direct current (dc)-conductivity measurements. The experimental results are compared and discussed with the aid of DFT simulations.Two-dimensional (2D) and 3D through-space 13C-13C homonuclear spin-diffusion techniques are powerful solid-state nucle