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This work presents a simple approach to access uniform fiber-like micelles by single-step crystalization-driven co-self-assembly of a polyferrocenyldimethylsilane (PFS) block copolymer with a trace of a PFS homopolymer. The length of micelles in the μm range could be controlled by changing the amount of homopolymer in the mixture.Symmetric bifunctional molecule-linked nanogap structures have been frequently used in nanoelectronics, it is still challenging to discriminate the phenomenon that happened at both interfacial regions with sub