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The results obtained confirm the high reliability of the developed model as it shows a skin-like surface behavior. This very interesting tool shows promising results concerning the study of the residual film present after product application or to study skin/product interactions.A ring-opening diphosphination of methylene- and vinylcyclopropanes with tetraaryldiphosphines (Ar2P-PAr2) has been developed to afford the corresponding 1,3-diphenylphosphinopropane- and 1,3-diphenylphosphinopentane-type bidentate ligands, respectively. The re