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Based on these results, it was clarified that the energy dissipation of the inorganic/organic DN ion gels was attributed to the internal fracture of the silica particle network.Transformation chemistry is a systematic methodology for achieving new atomically precise gold nanoclusters with specific physical and chemical properties. In this work, we have developed a new synthetic approach to prepare an aromatic thiolate-capped Au38(SNap)24 nanocluster via ligand exchange, size and structure transformation from the aliphatic thiolate-capp