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This work showed that the carbonate species have an enhanced catalytic impact with rate constants up to 1000 times larger than would be estimated by the Brønsted relationship for similar acids, which causes the oxidation by HOCl rate constant (kHOCl) to nearly double and oxidation by Cl2 to occur above pH 7 in high-alkalinity waters.High-stability, zirconium-based metal-organic frameworks are attractive as heterogeneous catalysts and as model supports for uniform arrays of subsequently constructed heterogeneous catalysts-for example, MO
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