https://www.selleckchem.com/pr....oducts/Epinephrine-b
The activation of carbon dioxide by metallylene [(dpp-bian)GaNa(DME)2] (dpp-bian = 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene) under mild conditions is described. Furthermore, the reaction of the activation complex [(dpp-bian)Ga(CO2)2Ga(dpp-bian)][Na(DME)2]2 (2) with diphenylketene, cyclohexyl isocyanate, and phenyl isocyanate leads to the elimination of carbon monoxide and the formation of derivatives of oxocarboxylic acid [(dpp-bian)GaOC(O)C(Ph)2C(CPh2)O][Na(DME)2] (6) and carbamate derivatives [(dp
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