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Understanding the physics behind the ejection dynamics in laser-induced forward transfer (LIFT) is of key importance in order to develop new printing techniques and overcome their limitations. In this work, a new jet-on-jet ejection phenomenon is presented and its physical origin is discussed. Time-resolved shadowgraphy imaging was employed to capture the ejection dynamics and is complemented with the photodiode intensity measurements in order to capture the light emitted by laser-induced plasma. A focus scan was conducted, which confirm