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A large volume collapse is observed associated with each phase transition, and the equations of state for different types of BiVO4 have been determined. These results provide new insights into the relationship between different structural types in the AVO4 family.Coalescence of droplets is an ubiquitous phenomenon in chemical, physical and biological systems. The process of merging of liquid objects has been studied during the past years experimentally and theoretically in different geometries. We introduce a unique system that allows a