https://www.selleckchem.com/pr....oducts/l-arginine-l-
The results show that if the electrostatic environment can be controlled, the product migration may be facilitated, which can improve the catalytic process.In this study, we explore strategies to resolve entangled reactivity modes. More specifically, we consider the competition between SN2 and E2 reaction pathways for alkyl halides and nucleophiles/bases. We first demonstrate that the emergence of an E2-preference is associated with an enhancement of the magnitude of the resonance stabilization in the transition-state (TS
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