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A doubly alkylene bridged 6,13-diphenylpentacene and analogously bridged azapentacenes were prepared; they are persistent. The doubly bridged azapentacenes display superior photochemical, oxidative and thermal stabilities compared to azapentacenes protected by bis(TIPS-ethynyl)-substituents-clipping an azaacene into a large ring is a viable complement in stabilization. Hard domestic water has been reported to worsen atopic eczema (AE) and may contribute to its development in early life. To review the literature on the relationship betwe
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